جداسازی ترکیب نیتروژنی کینولین از سوخت مدل با استفاده از کامپوزیت Fe3O4/TiO2/UiO-66

نوع مقاله : مقاله پژوهشی

نویسندگان

1 مهندسی شیمی، دانشکده فنی و مهندسی، دانشگاه ارومیه، ارومیه

2 گروه مهندسی شیمی، دانشکده فنی و مهندسی، دانشگاه ارومیه، ارومیه، ایران

10.22034/jfnc.2024.432249.1367

چکیده

ترکیبات نیتروژن­دار به‌واسطه اثرات منفی بر روی محیط‌زیست و پایداری کاتالیست باید از سوخت حذف شوند. در این پژوهش دی‌اکسید تیتانیوم و مگنتیت به چارچوب آلی- فلزی UiO-66 الحاق شدند و کامپوزیت Fe3O4/TiO2/UiO-66 به‌منظور استفاده در نیتروژن­زدایی سوخت مدل استفاده شد. چارچوب آلی- فلزی و کامپوزیت سنتز شده به کمک روش­های XRD، FTIR و BET تحلیل شدند. آنالیزهای تعیین مشخصات نشان داد که دی‌اکسید تیتانیوم و مگنتیت به‌خوبی به UiO-66 الحاق شده­اند. نتایج جذب سطحی نشان داد که کامپوزیت Fe3O4/TiO2/UiO-66، ppm 200 کینولین را در شش ساعت، با مقدار جاذب 005/0 گرم بر 5 میلی‌لیتر سوخت نرمال - هپتان حاوی کینولین در دمای 25 درجه سانتی­گراد به میزان 201 میلی‌گرم بر گرم جاذب حذف می­کند. طبق مقادیر مربع خطاها (R2) میزان انطباق نتایج تجربی با مدل­ هم‌دمای جذب لانگمویر مناسب بود. نتایج نشان داد که مدل شبه مرتبه دوم برای توصیف سینتیک مناسب­تر است. همچنین، سیستم جذب سطحی جدید ارائه شده را می­توان به‌عنوان یک روش جایگزین برای پالایش سوخت در نظر گرفت که دارای عملکرد بسیار کارآمد و سازگار با محیط‌زیست است.    
 

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Separation of quinoline nitrogen compound from model fuel using Fe3O4/TiO2/UiO-66 composite

نویسندگان [English]

  • Amin Alamdari 1
  • Fatemeh Hajipouralamdari 2
  • Abbas Aghaeinejad-Meybodi 2
1 Urmia University
2 Department of Chemical Engineering, Urmia University, Urmia, Iran
چکیده [English]

Nitrogenous compounds should be removed from fuel due to their negative effects on the environment and catalyst stability. In this research, titanium dioxide and magnetite were added to the UiO-66 metal-organic framework, and the Fe3O4/TiO2/UiO-66 composite was used to denitrogenation of the model fuel. The synthesized metal-organic framework and composite were analyzed by XRD, FTIR and BET methods. Characterization analyzes showed that titanium dioxide and magnetite were well incorporated into UiO-66. The adsorption results showed that the Fe3O4/TiO2/UiO-66 composite removes 200 ppm of quinoline in six hours, with 0.005 g adsorbent in 5 ml of n- heptane fuel containing quinoline at a temperature of 25 ºC at 201 mg.g-1 of adsorbent. According to the values of the squared errors (R2), the degree of conformity of the experimental results with the Langmuir adsorption isotherm model was suitable. The results showed that the pseudo-second order model is more suitable for describing the kinetics. Also, the presented new adsorption system can be considered as an alternative method for fuel refining, which has a very efficient and environmentally friendly performance.
.

کلیدواژه‌ها [English]

  • Metal-organic frameworks
  • UiO-66
  • Denitrogenation
  • Titanium dioxide
  • Magnetite

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سابقه مقاله

  • تاریخ دریافت: 03 دی 1402
  • تاریخ بازنگری: 25 اسفند 1402
  • تاریخ پذیرش: 10 فروردین 1403

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